Cambridge 0620 · Chemistry (0620) Core · Chapter 7 · The Periodic Table

The Periodic Table: Patterns, Groups and Trends

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Introduction

The Periodic Table looks like a wall of random boxes, but it's secretly the most organised thing in chemistry. Here's the cheat code: elements are lined up by proton number, and that lines up elements with the same number of outer electrons into the same column (Group). Since outer electrons run the chemistry, everything in a column behaves alike, so an element's address basically tells you its personality.

That means you can predict stuff you've never been taught: is it a metal, what charge its ion has, how reactive it is, even its colour and state. This is your fast refresh, not the full textbook: one key idea per topic, one worked example, and the exact move the marker wants. Let's read the table and predict some elements. 🔮


Reading the TableC8.1

The table is just elements in order of proton number, folded into a grid. Two numbers do all the work: the Group (the column, I–VIII) tells you the number of outer-shell electrons, and the Period (the row, 1–7) tells you the number of shells. Metals sit on the left, non-metals on the right, so going across a row you slide from metal to non-metal. Same column = same outer electrons = same vibe.

> 🔑 Key idea: Group = column = outer electrons. Period = row = number of shells. Metals left, non-metals right. Position tells you the chemistry. 🗺️


Worked Example: Name That Element TypeC8.1

Problem Phosphorus is in Group V. How many outer electrons does it have, and is it a metal or non-metal?

Step 1 Group number = outer electrons → Group V means 5 outer electrons.

Step 2 Group V is on the right → it's a non-metal.

5 outer electrons, non-metal. Read it straight off the column. ✅


Predicting Ions and FormulaeC8.1

Atoms want a full outer shell, so metals lose their few outer electrons (→ positive ions: Group I → 1+, II → 2+, III → 3+) and non-metals gain electrons (→ negative ions: Group VII → 1−, VI → 2−). To build a formula, just balance the charges so the whole thing is neutral. A 2+ paired with a 1− needs two of the 1− to cancel out, and you're done.

> 🔑 Key idea: Metals lose → + ions; non-metals gain → − ions. Charge comes from the Group, then balance + and − to get the formula. ⚖️


Worked Example: Build the FormulaC8.1

Problem M is in Group II, X is in Group VII. What's the formula of their compound?

Step 1 M → $\text{M}^{2+}$ (loses 2). X → $\text{X}^-$ (gains 1).

Step 2 One $\text{M}^{2+}$ needs two $\text{X}^-$ to balance → $\text{MX}_2$.

The charge size becomes the other one's subscript. 🎯


Group I: The Alkali MetalsC8.2

Group I (Li, Na, K…) are the alkali metals: 1 outer electron, makes a 1+ ion, and they're weirdly soft (cut with a knife) and low density (they float). Their party trick is reacting with water to make a metal hydroxide + hydrogen, which turns the water alkaline (indicator goes purple). You'll see the metal float, fizz and skate around the surface, and the equation is always $2\text{M} + 2\text{H}_2\text{O} \rightarrow 2\text{MOH} + \text{H}_2$.

> 🔑 Key idea: Alkali metals = 1 outer electron, soft, float. With water → hydroxide + hydrogen (alkaline). The gas is hydrogen. 🌊


Worked Example: Sodium Hits the WaterC8.2

Problem A small piece of sodium is dropped into cold water. Give three observations.

Step 1 It's less dense than water, so it floats and moves on the surface.

Step 2 It fizzes (hydrogen made) and melts into a ball (heat released).

Floats, fizzes, melts into a ball. The gas is hydrogen, not oxygen. ✅


Group I TrendsC8.2

Going down Group I the metals get more reactive, their melting point drops, and their density rises. That's all you need to predict a metal you've never met: caesium sits way below sodium, so it's more reactive, melts more easily and is denser. (The why — outer electron further out, easier to lose — is an Extended thing; at Core, just know the direction of the trend.)

> 🔑 Key idea: Down Group I: reactivity up ⬆️, melting point down ⬇️, density up ⬆️. Lower = more reactive. ⚡


Worked Example: Predict Down Group IC8.2

Problem From lithium to potassium, how do melting point, density and reactivity change? Does caesium react with water harder or softer than sodium?

Step 1 Down the group: melting point down, density up, reactivity up.

Step 2 Caesium is far below sodium → reacts more violently than sodium.

Follow the arrows one more step down. 🎯


Group VII: The HalogensC8.3

Group VII (F, Cl, Br, I) are the halogens: reactive non-metals with 7 outer electrons that gain 1 to make a 1− ion, and they travel as pairs (diatomic, like $\text{Cl}_2$). Going down, they get darker and more solid: chlorine is a yellow-green gas, bromine a red-brown liquid, iodine a grey-black solid. And here's the twist: unlike the metals, halogens get LESS reactive going down.

> 🔑 Key idea: Halogens = diatomic non-metals, 1− ions. Down the group: darker, more solid, and less reactive. 🎨


Worked Example: Iodine's LookC8.3

Problem What colour and state is iodine at room temperature, and how does it fit the Group VII trend?

Step 1 Iodine is a grey-black solid.

Step 2 Down the group: gas (Cl) → liquid (Br) → solid (I). Iodine being a solid fits perfectly.

The purple is iodine vapour — the solid is grey-black. ✅


Halogen DisplacementC8.3

Since reactivity is Cl > Br > I, a more reactive halogen displaces a less reactive halide from its salt. Chlorine kicks bromine out of potassium bromide, turning the solution orange: $\text{Cl}_2 + 2\text{KBr} \rightarrow 2\text{KCl} + \text{Br}_2$. Bromine can displace iodide, but iodine can't displace either — it's bottom of the pile.

> 🔑 Key idea: More reactive halogen displaces a less reactive halide (Cl > Br > I). Watch the solution change colour. 🥊


Worked Example: Chlorine vs BromideC8.3

Problem Chlorine solution is added to a solution with bromide ions. What do you see, and what's the equation?

Step 1 Chlorine is more reactive → it displaces bromine, so the solution turns orange (the bromine made).

Step 2 Equation: $\text{Cl}_2 + 2\text{KBr} \rightarrow 2\text{KCl} + \text{Br}_2$.

Orange = bromine. Keep $\text{Cl}_2$ and $\text{Br}_2$ as pairs. ✅


Transition ElementsC8.4

The transition elements (Fe, Cu, Zn…) are the big block in the middle, and they're metals with extra flair. Compared to Group I, they're hard, dense and high-melting, they form coloured compounds (Cu compounds blue, Fe compounds green), and they make great catalysts (iron in the Haber process). Group I metals are the opposite: soft, light and white-compound boring.

> 🔑 Key idea: Transition metals = hard, dense, coloured compounds, catalysts. That's what separates them from soft Group I. 🎨


Worked Example: Spot the Transition MetalC8.4

Problem An element has a melting point of 1555 °C, a brown oxide, and is used as a catalyst. Where in the table is it?

Step 1 High melting point + coloured (brown) oxide + catalyst = the transition signature.

Step 2 So it's a transition element.

Several transition clues at once → transition metal. 🎯


Transition vs Group IC8.4

Careful with "differences" questions: conducting electricity is shared with Group I (normal metal stuff), so it scores zero. The real differences are the transition specials: coloured compounds (copper goes blue, sodium stays white) and being harder, denser and catalytic. So copper makes a blue solution and sodium makes a colourless one — that's a genuine difference.

> 🔑 Key idea: "Difference" = a transition special (coloured compound, hard/dense, catalyst), NOT a shared metal property like conducting. 🟦


Worked Example: Copper's BlueC8.4

Problem Which makes a blue solution: copper(II) sulfate, sodium chloride or potassium nitrate? Give two ways copper differs from sodium.

Step 1 Transition metals make coloured compounds → copper(II) sulfate is the blue one.

Step 2 Copper makes coloured compounds (sodium's are white) and is hard and dense (sodium is soft).

Coloured compound = transition giveaway. ✅


Noble GasesC8.5

The noble gases (He, Ne, Ar…) are Group VIII/0 on the far right: single atoms (monatomic), colourless gases, and famously unreactive. The reason is one thing: a full outer shell (He has 2, the rest 8). With a full shell there's no reason to gain, lose or share electrons, so they just don't react. Plot twist: this is why every other element reacts — they're all trying to reach a full, noble-gas shell. Uses: helium in balloons (low density), argon in lamps and welding (inert), neon in signs.

> 🔑 Key idea: Noble gases = full outer shell → no need to gain/lose/share → unreactive. Everyone else reacts to copy them. 😎


Worked Example: Why So ChillC8.5

Problem Explain, using its electrons, why argon is unreactive.

Step 1 Argon has a full outer shell (2,8,8).

Step 2 A full shell → no tendency to gain, lose or share electrons → no reaction.

The mark is "full outer shell". ✅


Key Points to Remember

  • The table is ordered by proton number: Group (column) = outer electrons, Period (row) = number of shells. Metals left, non-metals right.
  • Ion charge comes from the Group: metals lose (1+, 2+, 3+), non-metals gain (1−, 2−). Balance + and − to get a formula.
  • Group I (alkali metals): soft, float, 1+ ions. With water → hydroxide + hydrogen ($2\text{M} + 2\text{H}_2\text{O} \rightarrow 2\text{MOH} + \text{H}_2$), giving an alkaline solution. Down the group: more reactive, lower melting point, higher density.
  • Group VII (halogens): diatomic non-metals, 1− ions. Down the group: darker, more solid, less reactive. Stronger halogen displaces weaker halide: $\text{Cl}_2 + 2\text{KBr} \rightarrow 2\text{KCl} + \text{Br}_2$.
  • Transition elements: hard, dense, coloured compounds, catalysts. Shared metal properties (conducting) aren't differences.
  • Noble gases: Group 0, monatomic, unreactive because of a full outer shell — the thing every other atom is chasing.

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